Have you removed the spindle nut? If you have and still can't get the drum off you may have a ridge on the brake drum preventing it from sliding past the shoes.
First try unadjusting the brake (all the way) by using a large flat bladed screwdriver in the slot behind the backing plate, moving the star either up or down until it stops (the correct direction is the one that doesn't lock up the drum). If the drum still won't come off, you'll need to chisel or grind off the spring keeper heads on the back side of the backing plate...this way the shoes will be free to let the drum pull off.
More info here