Hi Baycationer,
First, you may want to do a search - this topic has been covered A LOT.
The quick answer to you question is that the positive leads from the batteries go to the switch and the positive wire(s) from your current single battery go the the common terminal on the switch. The negative leads of your batteries are jumpered and the negative wire currently on you single battery is left in place.
In operation you can run from either battery or both and you can switch from #1 to both to #2 - BUT NEVER TO OFF when the engine is running.
Blue Sea systems, who probably is the OEM on your switch, has a site with lots of info:
www.bluesea.com
BTW - I'm assuming that your trolling motor hookup is a 12volt.
Edit - seems that mole2 was writing at the same time I was - I assumed you were looking for a 2 battery system for starting and house. If that's not the case the setup would be different. Always interesting how we get locked in to our views - I hadn't really considered mole2's point. That's what I like about this site - lots of different experiences and points of view.